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21. "All at Once"
"All at Once," from Whitney's 1985 debut, was only released as a single overseas, but it's still a key moment in her career, one of her first massive, pop-diva ballads, paving roads for Mariah, Celine and others to drive down. The slow start, the big finish, the key modulation at the end, the impossible high notes—all the ingredients are there.
(Photo: Jan Persson/Redferns/Getty Images)
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