Styled to Rock: Rihanna’s Hottest Rock Star Moments

If it doesn't rock, then Ms. Fenty won't even bring it.

"Pour It Up," Rihanna - After Juicy J's "Bandz a Make Her Dance" took off, Rihanna turned out Mike WiLL Made It's "Pour It Up." He produced both songs and with a similar beat he won, twice! (Photo: WENN.com)

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Rockstar 101 - Styled to Rock premieres Oct. 25 on Bravo, and what better way to celebrate Rihanna’s new gig than taking a look back at her sexiest rock star moments. Prepare to gawk, she's hot! By Metanoya Z. Webb (Photo: WENN.com)

Girl on Fire - Rihanna literally sets the stage a blaze in a color block Adam Selman bustier and matching pants.  (Photo: Rihanna via Instagram)

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Girl on Fire - Rihanna literally sets the stage a blaze in a color block Adam Selman bustier and matching pants. (Photo: Rihanna via Instagram)

Photo By Photo: Rihanna via Instagram

Down on Bended Knees  - The provocative singer whips her hair back and forth while in Hanover. Her fans look like they’re in a trance. Don't front, you would be too.  (Photo: Sonja van Kampen/Future Image/WENN.com)

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Down on Bended Knees - The provocative singer whips her hair back and forth while in Hanover. Her fans look like they’re in a trance. Don't front, you would be too.  (Photo: Sonja van Kampen/Future Image/WENN.com)

Rihanna, @badgalriri - Rihanna may have been shy about giving the most on that surfboard, but her fans are certainly used to her not holding back when she performs, like in this snapshot she pulled from a show in Australia.(Photo: Stefan Gosatti/Getty Images)

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Bad Gal - Rihanna's rude lyrics match her racy image. The Styled to Rock star dutty wines in custom Givenchy couture, a gold shark tooth necklace and studded thigh-high boots—haute!(Photo: Stefan Gosatti/Getty Images)

Get Low - Let’s pretend like our focus is on Rihanna's flatforms, fishnets and polka-dot tee—and not her backside.  (Photo: Chris McGrath/Getty Images for Singapore GP)

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Get Low - Let’s pretend like our focus is on Rihanna's flatforms, fishnets and polka-dot tee—and not her backside. (Photo: Chris McGrath/Getty Images for Singapore GP)

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Stadium Killa - Tongue out, hands up, it’s no surprise that RiRi likes to party—in style that is. Peep her custom white Louboutin footwear and slick rockstar cut.    (Photo: Splash News)

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Stadium Killa - Tongue out, hands up, it’s no surprise that RiRi likes to party—in style that is. Peep her custom white Louboutin footwear and slick rockstar cut.  (Photo: Splash News)

Naughty Girl - The Bajan blonde seduces fans while performing in Monaco, rocking a pleated white tennis dress with a plunging neckline, satin over-the-knee boots and vibrant red lips and tips. Peep her facial expression—Ms. Fenty means business.   (Photo: VALERY HACHE/AFP/Getty Images)

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Naughty Girl - The Bajan blonde seduces fans while performing in Monaco, rocking a pleated white tennis dress with a plunging neckline, satin over-the-knee boots and vibrant red lips and tips. Peep her facial expression—Ms. Fenty means business. (Photo: VALERY HACHE/AFP/Getty Images)

Bottoms Up - In typical rude gal fashion, RiRi bites her lip and screws up her face while squatting low and admiring her enviable assets.   (Photo: Simone Joyner/Getty Images)

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Bottoms Up - In typical rude gal fashion, RiRi bites her lip and screws up her face while squatting low and admiring her enviable assets.  (Photo: Simone Joyner/Getty Images)

Rihanna - After emerging as a teenager with dance hits like "Pon De Replay" and "S.O.S.," Rihanna has flipped her reputation from a pop princess to bad gal. In addition to her blunt-smoking, strip club-loving antics, she's been up front about this change in her music, releasing albums like Good Girl Gone Bad, Rated R, and Unapologetic. (Photo: Mike Lawrie/Getty Images)

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Number 1 Stunna  - From the vampy lip to the flowing blonde curls, Rihanna hit a high note with this one.(Photo: Mike Lawrie/Getty Images)

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One Leg Up - She has her signature go-to dancemoves, but it's her undeniable beauty and monochromatic outfit that’s stealing our attention.If it doesn't rock, Rihanna won't even bring it.(Photo: FADEL SENNA/AFP/Getty Images)